Evaluation of mechanical and barrier properties of films based on eva / clay
EVA, clay, mechanical properties, barrier properties
Polymer films based on ethylene vinyl acetate (EVA) were produced in this
work, as well as nanocomposites of EVA and Cloisite 20A clay. These films and
nanocomposites were produced with two different solvent types, chloroform and
tetrahydrofuran by the solvent evaporation technique. Compositions 3% and 5%
clay by weight with respect to the polymer weight were used for the production of
nanocomposites, both using chloroform as solvent, such as tetrahydrofuran. To
evaluate the influence of the type of solvent and the addition of clay in the polymer
matrix on the properties of the films the techniques of diffraction of x - ray, Fourier
transform infrared, contact angle and water vapor transmission rate were used.
The x-ray diffraction showed a dispersion of the clay in the films. The Fourier
transform infrared showed that the addition of clay as well as the use of the
different solvents did not modify the characteristic bands of the film. From the
results obtained by the water vapor transmission test an increase of the barrier
properties of the films with the addition of clay and a greater homogeneity in the
results obtained using tetrahydrofuran as solvent can be verified. The contact angle
characterization showed that the addition of clay in the polymer matrix caused a
change in the hydrophobicity of the films.