Banca de QUALIFICAÇÃO: MATHEUS DE MEDEIROS TAVARES

Uma banca de QUALIFICAÇÃO de DOUTORADO foi cadastrada pelo programa.
STUDENT : MATHEUS DE MEDEIROS TAVARES
DATE: 28/02/2022
TIME: 13:00
LOCAL: Sala Virtual
TITLE:

STUDY OF MICROSTRUCTURE AND PROPERTIES OF THE HARDMETAL WC-(Fe-Nb/NbH-C)

KEY WORDS:

cemented carbide, alternative binder, sintering, hardness, niobium, SPS.

PAGES: 88
BIG AREA: Engenharias
AREA: Engenharia de Materiais e Metalúrgica
SUBÁREA: Metalurgia de Transformação
SPECIALTY: Metalurgia de Pó
SUMMARY:

The search for alternative binders for hardmetals, also called cemented carbides, has moved the scientific community. Cobalt is the element traditionally used as a binder phase in cemented carbide industry. However, this material is considered rare, hard to obtain and, consequently, expensive, in addition to being the target of studies that relate it to carcinogenic agents. Alternative Fe-based binders have been widely studied and applied in selected applications. An unprecedented addition to this ligand would be the use of niobium, a metal of high global interest, few explored and abundant in Brazilian territory. This work aims to investigate the properties of the Fe-Nb/NbH-C system, using it as an alternative binder to produce WC-(Fe-Nb/NbH-C) cemented carbides. For this purpose, ring and planetary milling techniques were used, using controlled atmosphere sintering and spark plasma sintering (SPS) techniques in a sintering temperature range from 1150ºC to 1450ºC. To evaluate the composition, microstructure and properties, the ThermoCalc software was used, in addition to the XRD, MO, SEM, EDS, density, Vickers hardness and fracture toughness techniques. The preliminary results pointed to planetary mill as the most efficient method for mixing and particle size reduction, resulting in samples with better mechanical properties. Controlled atmosphere sintering for this application proved to be unfeasible, on the other hand, spark plasma sintering proved to be an efficient method for the production of densified samples. The sintering temperature of 1250ºC provided the best microstructure and properties results for all SPS processing conditions. Replacing Nb for NbH, it was possible to obtain samples with more homogeneous and densified microstructure by reducing the size of the niobium particles, absence of eta phase, and a remarkable microstructural gradient formation, as well as hardness values of up to 1620Hv, meaning an increase of approximately 15% in relation to pure niobium compositions. The results of this study are promising, but still require further investigations to prove the feasibility of applying these compositions in industrial scale applications.

BANKING MEMBERS:
Presidente - 345842 - UILAME UMBELINO GOMES
Interno - 1350249 - RUBENS MARIBONDO DO NASCIMENTO
Externo ao Programa - 2414250 - MEYSAM MASHHADIKARIMI
Externa à Instituição - MARIA JOSÉ SANTOS LIMA - UFRN