Chemical and mineralogical characterization of aluminum phosphates from the Samambaia Fault, Rio Grande do Norte
Aluminum phosphates; Variscite; Crandallite; Samambaia Fault
The Samambaia Fault, one of the most significant seismogenic structures in Northeast Brazil, hosts aluminum phosphate mineralizations within fractures and quartz veins associated with hydrothermal events. This study provides a textural and chemical characterization of these mineralizations, focusing on variscite, crandallite, millisite/wardite, and kaolinite, using techniques such as XRD, QEMScan, SEM/EDS, and EPMA. Variscite is the dominant phosphate, showing a compositional transition between variscite and Fe-variscite. Calcium-rich phosphates indicate interactions with Ca- and Fe-rich fluids, while clay minerals suggest intense supergene processes. The proposed paragenetic sequence reveals that the geochemical evolution of the system was controlled by meteoric fluid percolation and fluid-rock interaction. These findings contribute to understanding mineralization processes in tectonically active zones and their implications for silicified and fractured reservoir systems.